If you parallel glaze a double glazed window, there is a degree of transmission caused by the outer pane vibration "pumping" the cavity air and in turn exciting the inner panel severely limiting isolation.
To avoid this in isolation windows for recording studios etc, the panes are arranged to be non parallel by offsetting one pane vertically in the frame by about 75-100mm, and the other horizontally by a similar amount. For extreme isolation, a third pane is sometimes added between.